Most email providers cap attachments at around 25MB, and it's remarkably easy for a PDF — especially one with scanned pages or embedded photos — to blow past that without looking unusually large when you glance at it.
Why it happened
In almost every case, embedded images are the reason. A scanned document is essentially one image per page at whatever resolution the scanner used; a report with a handful of high-resolution photos or charts carries that same weight. Actual text content takes up very little space by comparison, so the size is almost always coming from images, not the words on the page.
The fix
Compressing the PDF re-encodes its embedded images at a lower — but still readable — quality setting, which typically brings a document from well over the limit down to a fraction of its original size. This is different from simply re-saving the file, which usually repackages the images at their existing resolution without actually shrinking them.
If compression alone isn't enough
For a genuinely large document — a lengthy scanned book, or a report with dozens of full-resolution images — splitting it into a couple of smaller files and sending them separately (or as a linked download) may be the more practical route than chasing an aggressive compression setting that starts to hurt readability.
Compress PDF handles the re-encoding directly in your browser, showing the resulting file size before you download. If splitting is the better route for a very large document, Split PDF breaks it into smaller pieces, and if you're recombining a set of already-compressed files, Merge PDF puts them back into one document.